Searles D J, Evans D J
Department of Chemistry, University of Queensland, Brisbane, Queensland 4072, Australia.
Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics. 1999 Jul;60(1):159-64. doi: 10.1103/physreve.60.159.
The fluctuation theorem describes the probability ratio of observing trajectories that satisfy or violate the second law of thermodynamics. It has been proved in a number of different ways for thermostatted deterministic nonequilibrium systems. In the present paper we show that the fluctuation theorem is also valid for a class of stochastic nonequilibrium systems. The theorem is therefore not reliant on the reversibility or the determinism of the underlying dynamics. Numerical tests verify the theoretical result.
涨落定理描述了观察满足或违反热力学第二定律的轨迹的概率比。对于恒温确定性非平衡系统,已经用多种不同方法证明了该定理。在本文中,我们表明涨落定理对于一类随机非平衡系统也成立。因此,该定理并不依赖于基础动力学的可逆性或确定性。数值测试验证了理论结果。