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The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids.

作者信息

Tavasli Mustafa, O'Hagan David, Pearson Christopher, Petty Michael C

机构信息

School of Chemistry, University of St Andrews, Centre for Biomolecular Sciences, Haugh, North St Andrews, Fife, UK KY16 9ST.

出版信息

Chem Commun (Camb). 2002 Jun 7(11):1226-7. doi: 10.1039/b202891c.

DOI:10.1039/b202891c
PMID:12109094
Abstract

(+/-)-Erythro- and (+/-)-threo-9,10-difluorostearic acids, which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.

摘要

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