Akakabe Yoshihiko, Matsui Kenji, Kajiwara Tadahiko
Department of Biological Chemistry, Faculty of Agriculture, Yamaguchi University, 1677-1 Yoshida, Yamaguchi, Japan.
Bioorg Med Chem. 2002 Oct;10(10):3171-3. doi: 10.1016/s0968-0896(02)00212-2.
When linoleic and linolenic acid were incubated with a crude enzyme of marine green alga Ulva conglobata, the corresponding (R)-9-hydroperoxy-(10E, 12Z)-10, 12-octadecadienoic acid [(R)-9-HPODE] and (R)-9-hydroperoxy-(10E, 12Z, 15Z)-10, 12, 15-octadecatrienoic acid [(R)-9-HPOTrE] were formed with a high enantiomeric excess (>99%), respectively.
当亚油酸和亚麻酸与海洋绿藻孔石莼的粗酶一起温育时，分别形成了对映体过量值较高（>99%）的相应的（R）-9-氢过氧-（10E，12Z）-10，12-十八碳二烯酸[（R）-9-HPODE]和（R）-9-氢过氧-（10E，12Z，15Z）-10，12，15-十八碳三烯酸[（R）-9-HPOTrE]。
