亚磺酰胺催化醇类与无水氯胺 -T 氧化生成相应的羰基化合物。
Sulfenamide catalyzed oxidation of alcohols to the corresponding carbonyl compounds with anhydrous chloramine-T.
作者信息
Kitagawa Hideo, Mukaiyama Teruaki
机构信息
The Kitasato Institute, Center for Basic Research, Tokyo, Japan.
出版信息
Chem Pharm Bull (Tokyo). 2002 Sep;50(9):1276-9. doi: 10.1248/cpb.50.1276.
PMID:12237553
Abstract
N-tert-Butylbenzenesulfenamide (1) catalyzed oxidation of various alcohols with stoichiometric amount of anhydrous chloramines-T (2) proceeded smoothly at room temperature to afford the corresponding carbonyl compounds in good yields.
摘要
N-叔丁基苯亚磺酰胺（1）在室温下能顺利催化各种醇与化学计量的无水氯胺-T（2）发生氧化反应，以良好的产率得到相应的羰基化合物。
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