碘催化糖烯与氯胺 -T 的一锅法双胺化反应：一种用于 N - 糖肽合成的 2 - 氨基 -β - 糖基胺的新方法
Iodine catalyzed one-pot diamination of glycals with chloramine-T: a new approach to 2-amino-beta-glycosylamines for applications in N-glycopeptide synthesis.
作者信息
Kumar Vipin, Ramesh Namakkal G
机构信息
Department of Chemistry, Indian Institute of Technology - Delhi, Hauz Khas, New Delhi - 110016, India.
出版信息
Chem Commun (Camb). 2006 Dec 21(47):4952-4. doi: 10.1039/b612151a. Epub 2006 Oct 9.
DOI:10.1039/b612151a
PMID:17136258
Abstract
Iodine catalyzes a facile one-pot direct diamination of glycals with chloramine-T to afford stereoselectively 2-amino-beta-glycosylamine derivatives that serve as convenient precursors for the synthesis of N-linked glycopeptides.
摘要
碘催化了糖烯与氯胺 -T 的简便一锅法直接双胺化反应，以立体选择性地得到 2-氨基-β-糖基胺衍生物，这些衍生物是合成 N-连接糖肽的便利前体。
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