Zhang Q M, Li Hengfeng, Poh Martin, Xia Feng, Cheng Z-Y, Xu Haisheng, Huang Cheng
Materials Research Institute and Electrical Engineering Department, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.
Nature. 2002 Sep 19;419(6904):284-7. doi: 10.1038/nature01021.
Electroactive polymers (EAPs) can behave as actuators, changing their shape in response to electrical stimulation. EAPs that are controlled by external electric fields--referred to here as field-type EAPs--include ferroelectric polymers, electrostrictive polymers, dielectric elastomers and liquid crystal polymers. Field-type EAPs can exhibit fast response speeds, low hysteresis and strain levels far above those of traditional piezoelectric materials, with elastic energy densities even higher than those of piezoceramics. However, these polymers also require a high field (>70 V micro m(-1)) to generate such high elastic energy densities (>0.1 J cm(-3); refs 4, 5, 9, 10). Here we report a new class of all-organic field-type EAP composites, which can exhibit high elastic energy densities induced by an electric field of only 13 V micro m(-1). The composites are fabricated from an organic filler material possessing very high dielectric constant dispersed in an electrostrictive polymer matrix. The composites can exhibit high net dielectric constants while retaining the flexibility of the matrix. These all-organic actuators could find applications as artificial muscles, 'smart skins' for drag reduction, and in microfluidic systems for drug delivery.
电活性聚合物(EAPs)可作为致动器,在电刺激下改变其形状。由外部电场控制的EAPs(此处称为场型EAPs)包括铁电聚合物、电致伸缩聚合物、介电弹性体和液晶聚合物。场型EAPs可表现出快速的响应速度、低滞后性以及远高于传统压电材料的应变水平,其弹性能量密度甚至高于压电陶瓷。然而,这些聚合物也需要高电场(>70 Vμm⁻¹)才能产生如此高的弹性能量密度(>0.1 J cm⁻³;参考文献4、5、9、10)。在此,我们报道了一类新型的全有机场型EAP复合材料,其在仅13 Vμm⁻¹的电场作用下就能展现出高弹性能量密度。这些复合材料由一种具有非常高介电常数的有机填充材料制成,该材料分散在电致伸缩聚合物基体中。这些复合材料在保持基体柔韧性的同时可表现出高的净介电常数。这些全有机致动器可应用于人造肌肉、用于减阻的“智能皮肤”以及用于药物输送的微流体系统。