Dearden Michael J, Firkin Catherine R, Hermet Jean-Paul R, O'Brien Peter
Department of Chemistry, University of York, Heslington, York YO10 5DD, U.K.
J Am Chem Soc. 2002 Oct 9;124(40):11870-1. doi: 10.1021/ja027774v.
A "(+)-sparteine-like" chiral diamine, readily synthesized in three steps from (-)-cytisine, has been evaluated in four different asymmetric transformations; in each case, selectivity in an enantiocomplementary fashion to (-)-sparteine was observed.
一种“（+）-鹰爪豆碱类”手性二胺，可由（-）-金雀花碱经三步轻松合成，已在四种不同的不对称转化反应中进行了评估；在每种情况下，均观察到其对映选择性与（-）-鹰爪豆碱呈对映互补。
