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胺的C-H键官能团化：多种方法的图形概述

C-H Bond Functionalization of Amines: A Graphical Overview of Diverse Methods.

作者信息

Dutta Subhradeep, Li Bowen, Rickertsen Dillon R L, Valles Daniel A, Seidel Daniel

机构信息

Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville, FL 32611, USA.

出版信息

SynOpen. 2021;5(3):173-228. doi: 10.1055/s-0040-1706051. Epub 2021 Aug 12.

DOI:10.1055/s-0040-1706051
PMID:34825124
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8612105/
Abstract

This Graphical Review provides a concise overview of the manifold and mechanistically diverse methods that enable the functionalization of sp C-H bonds in amines and their derivatives.

摘要

本图形综述简要概述了多种方法及其不同的作用机制，这些方法能够实现胺类及其衍生物中sp C-H键的官能化。

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5
Iron-catalyzed α-C-H functionalization of π-bonds: cross-dehydrogenative coupling and mechanistic insights.铁催化的π键α-C-H官能团化：交叉脱氢偶联及机理研究
Chem Sci. 2020 Oct 16;11(45):12316-12322. doi: 10.1039/d0sc05091a.
6
Sulfamides direct radical-mediated chlorination of aliphatic C-H bonds.磺胺类化合物可直接实现自由基介导的脂肪族碳氢键氯化反应。
Chem Sci. 2019 Nov 8;11(1):217-223. doi: 10.1039/c9sc03428e.
7
α-C-H/N-H Annulation of Alicyclic Amines via Transient Imines: Preparation of Polycyclic Lactams.α-C-H/N-H 环化芳胺反应：通过瞬态亚胺制备多环内酰胺。
Org Lett. 2021 May 7;23(9):3729-3734. doi: 10.1021/acs.orglett.1c01125. Epub 2021 Apr 21.
8
Palladium-Mediated C -H Functionalization of Alicyclic Amines.钯介导的环状胺的 C-H 官能化反应。
Angew Chem Int Ed Engl. 2021 May 10;60(20):11227-11230. doi: 10.1002/anie.202101782. Epub 2021 Apr 8.
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Key Mechanistic Features of the Silver(I)-Mediated Deconstructive Fluorination of Cyclic Amines: Multistate Reactivity versus Single-Electron Transfer.银（I）介导的环状胺解构氟化反应的关键机制特征：多态反应与单电子转移。
J Am Chem Soc. 2021 Mar 17;143(10):3889-3900. doi: 10.1021/jacs.0c13061. Epub 2021 Mar 3.
10
C-H Activation: Toward Sustainability and Applications.碳-氢活化：迈向可持续发展与应用
ACS Cent Sci. 2021 Feb 24;7(2):245-261. doi: 10.1021/acscentsci.0c01413. Epub 2021 Feb 2.