Vanchura Britt A, He Pingang, Antochshuk Valentyn, Jaroniec Mietek, Ferryman Amy, Barbash Dmytro, Fulghum Julia E, Huang Songping D
Department of Chemistry, Kent State University, Kent, Ohio 44240, USA.
J Am Chem Soc. 2002 Oct 16;124(41):12090-1. doi: 10.1021/ja025786a.
A series of novel mesostructured lamellar molybdenum disulfides with the d spacings from 17 to 30 A can be prepared by the reaction of Mo(CO)6 with elemental sulfur using a molten n-alkylamine as the solvent as well as the template at 140 degrees C. Such intercalated phases can be transformed into mesoporous molybdenum disulfides by slow thermal treatments at 200 degrees C.
通过在140℃下以熔融的正烷基胺作为溶剂和模板，使Mo(CO)₆与单质硫反应，可以制备出一系列d间距为17至30埃的新型介孔层状二硫化钼。通过在200℃下进行缓慢热处理，这些插层相可以转变为介孔二硫化钼。
