氢氟碳化合物245fa：炔烃化学中一种多功能的新型合成子。
Hydrofluorocarbon 245fa: a versatile new synthon in alkyne chemistry.
作者信息
Brisdon Alan K, Crossley Ian R
机构信息
Department of Chemistry, UMIST, P.O. Box 88, Manchester M60 1QD, UK.
出版信息
Chem Commun (Camb). 2002 Oct 21(20):2420-1. doi: 10.1039/b207979h.
DOI:10.1039/b207979h
PMID:12430470
Abstract
The CFC replacement 1,1,1,3,3-pentafluoropropane (HFC 245 fa) has been established as a convenient source of trifluoropropynyllithium under mild conditions; a range of novel and known trifluoropropynyl-containing systems has been prepared in a one-pot procedure.
摘要
CFC替代物1,1,1,3,3-五氟丙烷（HFC 245 fa）已被证实是在温和条件下制备三氟丙炔基锂的便利原料；一系列新型和已知的含三氟丙炔基体系已通过一锅法制备出来。
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