Rapsomanikis S, Zerefos C, Melas D, Tsangas N
Environmental Engineering Department, Democritus University of Thrace, 67100 Xanthi, Greece.
Environ Technol. 2002 Oct;23(10):1119-25. doi: 10.1080/09593332308618341.
Between March 24 and June 10, 1999 a large number of chemicals were ejected into the atmosphere because of air strikes on chemical industries and oil storage facilities in former Yugoslavia. Chemicals released into the atmosphere under suitable meteorological conditions can be transported across borders to large distances. The releases may have contained not only conventional air pollutants but also semi-volatile organic compounds (SOCs) which include dioxins, furans, PCBs and PAHs, all known to be hazardous to health. A measuring programme was initiated at Democritus University Thrace, Greece to monitor the chemical characteristics of atmospheric aerosol during February, March and April 1999. Particulate matter (aerosol) was collected on filters and was analysed using high-resolution gas chromatography coupled to high-resolution mass spectrometry for their content in SOCs. In the present work we show evidence of two events with three to twenty fold increased SOCs in the atmosphere of Northern Greece which were associated with air masses transported from the conflict area, following the destruction of chemical plants and oil storage facilities.
1999年3月24日至6月10日期间,由于对前南斯拉夫的化学工业和石油储存设施进行空袭,大量化学物质被排放到大气中。在适宜的气象条件下释放到大气中的化学物质可跨境远距离传输。这些释放物可能不仅包含常规空气污染物,还包括半挥发性有机化合物(SOCs),其中有二噁英、呋喃、多氯联苯和多环芳烃,所有这些都已知对健康有害。希腊色雷斯德谟克利特大学启动了一项测量计划,以监测1999年2月、3月和4月期间大气气溶胶的化学特性。在滤膜上收集颗粒物(气溶胶),并使用高分辨率气相色谱-高分辨率质谱联用仪分析其SOCs含量。在本研究中,我们展示了希腊北部大气中SOCs增加三至二十倍的两个事件的证据,这些事件与化工厂和石油储存设施遭到破坏后从冲突地区输送来的气团有关。