Endres Frank
University of Karlsruhe, Institute for Physical Chemistry, 76128 Karlsruhe, Germany.
Chemphyschem. 2002 Feb 15;3(2):145-54. doi: 10.1002/1439-7641(20020215)3:2<144::aid-cphc144>3.0.co;2-#.
In a wider sense, ionic liquids are molten salts that melt below 100 degrees C. As their name suggests, they are solely composed of ions and many combinations of organic and/or inorganic cations and anions exist. Depending on the systems they can reach electrochemical windows of more than 4 V and thus they give access to a number of elements that cannot be electrodeposited from aqueous solutions, such as the light and refractory metals, as well as elemental and compound semiconductors. Presumably, ionic liquids will become important for electrochemical nanotechnology.
从更广泛的意义上讲,离子液体是熔点低于100摄氏度的熔盐。顾名思义,它们仅由离子组成,存在许多有机和/或无机阳离子与阴离子的组合。根据体系不同,它们可达到超过4V的电化学窗口,因此能够实现一些无法从水溶液中电沉积的元素的电沉积,如轻金属和难熔金属,以及元素半导体和化合物半导体。据推测,离子液体对电化学纳米技术将变得至关重要。