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Preparation and reactivity of O2-sulfonated diazeniumdiolates.

作者信息

D'Sa Raechelle A, Wang Yuhong, Ruane Patrick H, Showalter Brett M, Saavedra Joseph E, Davies Keith M, Citro Michael L, Booth Melissa N, Keefer Larry K, Toscano John P

机构信息

Department of Chemistry, Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, USA.

出版信息

J Org Chem. 2003 Jan 24;68(2):656-7. doi: 10.1021/jo026656n.

Abstract

We report the facile preparation of O2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O2-substituted diazeniumdiolates available for potential applications in research and medicine.

摘要

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