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紫菀根中的脑苷脂和萜烯糖苷。

Cerebrosides and terpene glycosides from the root of Aster scaber.

作者信息

Kwon Hak Cheol, Cho Ock Ryun, Lee Kang Choon, Lee Kang Ro

机构信息

College of Pharmacy, Sung Kyun Kwan University, Suwon 440-746, Korea.

出版信息

Arch Pharm Res. 2003 Feb;26(2):132-7. doi: 10.1007/BF02976658.

Abstract

Three cerebrosides 2, 3, and 5 and two terpene glycosides 1 and 4 have been isolated from the methanol extract of the root of Aster scaber. Their structures were determined as 3-O-beta-D-glucuronopyranosyl-oleanolic acid methyl ester (1), (2S, 3S, 4R, 2'R, 8Z, 15'Z)-N-2'-hydroxy-15'-tetracosenoyl-1-O-beta-D-glucopyranosyl-4-hydroxy-8-sphingenine (2), (2S, 3S, 4R, 8Z)-N-octadecanoyl-1-O-beta-D-glucopyranosyl-4-hydroxy-8-sphingenine (3), 1alpha-hydroxy-6beta-O-beta-D-glucosyl-eudesm-3-ene (4), and (2S, 3S, 4R, 2'R, 8Z)-N-2'-hydroxy-hexadecanoyl-1-O-beta-D-glucopyranosyl-4-hydroxy-8-sphingenine (5) on the basis of spectroscopic methods.

摘要

从东风菜根的甲醇提取物中分离出了三种脑苷脂2、3和5以及两种萜烯糖苷1和4。基于光谱方法,它们的结构被确定为3 - O - β - D - 葡糖醛酸吡喃糖基齐墩果酸甲酯(1)、(2S, 3S, 4R, 2'R, 8Z, 15'Z) - N - 2' - 羟基 - 15' - 二十四碳烯酰基 - 1 - O - β - D - 吡喃葡萄糖基 - 4 - 羟基 - 8 - 鞘氨醇(2)、(2S, 3S, 4R, 8Z) - N - 十八烷酰基 - 1 - O - β - D - 吡喃葡萄糖基 - 4 - 羟基 - 8 - 鞘氨醇(3)、1α - 羟基 - 6β - O - β - D - 葡糖基 - 桉叶 - 3 - 烯(4)和(2S, 3S, 4R, 2'R, 8Z) - N - 2' - 羟基 - 十六烷酰基 -

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