Leconte M, Martin J, Rakotomalala N, Salin D
Laboratoire Fluides Automatique et Systèmes Thermiques, Universités Pierre et Marie Curie and Paris Sud, C.N.R.S. (UMR 7608) Bâtiment 502, Campus Universitaire, 91405 Orsay Cedex, France.
Phys Rev Lett. 2003 Mar 28;90(12):128302. doi: 10.1103/PhysRevLett.90.128302. Epub 2003 Mar 27.
Autocatalytic reaction between reacted and unreacted species may propagate as solitary waves, namely, at a constant front velocity and with a stationary concentration profile, resulting from a balance between molecular diffusion and chemical reaction. The effect of advective flow on the autocatalytic reaction between iodate and arsenous acid in cylindrical tubes and Hele-Shaw cells is analyzed experimentally and numerically using lattice Bhatnagar-Gross-Krook simulations. We do observe the existence of solitary waves with concentration profiles exhibiting a cusp and we delineate the eikonal and mixing regimes recently predicted.
已反应物种和未反应物种之间的自催化反应可能以孤立波的形式传播,即,在分子扩散和化学反应之间的平衡作用下,以恒定的前沿速度和固定的浓度分布进行传播。使用格子玻尔兹曼 Bhatnagar-Gross-Krook 模拟,通过实验和数值分析了平流对圆柱形管和赫勒-肖细胞中碘酸盐和亚砷酸之间自催化反应的影响。我们确实观察到了浓度分布呈现尖点的孤立波的存在,并描绘了最近预测的程函和混合区域。