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Fluctuation-dissipation relations and energy landscape in an out-of-equilibrium strong-glass-forming liquid.

作者信息

Scala Antonio, Valeriani Chantal, Sciortino Francesco, Tartaglia Piero

机构信息

Dipartimento di Fisica e INFM, Universitá di Roma La Sapienza, Piazzale Aldo Moro 2, I-00185, Roma, Italy.

出版信息

Phys Rev Lett. 2003 Mar 21;90(11):115503. doi: 10.1103/PhysRevLett.90.115503. Epub 2003 Mar 18.

Abstract

We study the out-of-equilibrium dynamics following a temperature jump in a model for silica, a strong liquid, and compare it with the well known case of fragile liquids. We calculate the fluctuation-dissipation relation, from which it is possible to estimate an effective temperature T(eff) associated with the slow out-of-equilibrium structural degrees of freedom. We find the striking and unexplained result that, different from the fragile liquid cases, T(eff) is smaller than the bath temperature.

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