Lim Teng-Teeh, Heber Albert J, Ni Ji-Qin, Sutton Alan L, Shao Ping
Agricultural and Biological Engineering Dep., Purdue Univ., West Lafayette, IN 47907, USA.
J Environ Qual. 2003 Mar-Apr;32(2):406-16. doi: 10.2134/jeq2003.4060.
Odor and gas release from anaerobic lagoons for treating swine waste affect air quality in neighboring communities but rates of release are not well documented. A buoyant convective flux chamber (BCFC) was used to determine the effect of lagoon loading rate on measured odor and gas releases from two primary lagoons at a simulated wind speed of 1.0 m s(-1). Concentrations of ammonia (NH3), hydrogen sulfide (H2S), carbon dioxide (CO2), sulfur dioxide (SO2), and nitric oxide (NO) in 50-L air samples were measured. A panel of human subjects, whose sensitivity was verified with a certified reference odorant, evaluated odor concentration, intensity, and hedonic tone. Geometric mean odor concentrations of BCFC inlet and outlet samples and of downwind berm samples were 168 +/- 44 (mean +/- 95% confidence interval), 262 +/- 60, and 114 +/- 38 OU(E) m(-3) (OU(E), European odor unit, equivalent to 123 microg n-butanol), respectively. The overall geometric mean odor release was 2.3 +/- 1.5 OU(E) s(-1) m(-2) (1.5 +/- 0.9 OU s(-1) m(-2)). The live mass specific geometric mean odor release was 13.5 OU(E) s(-1) AU(-1) (animal unit = 500 kg live body mass). Overall mean NH3, H2S, CO2 and SO2 releases were 101 +/- 24, 5.7 +/- 2.0, 852 +/- 307, and 0.5 +/- 0.4 microg s(-1) m(-2), respectively. Nitric oxide was not detected. Odor concentrations were directly proportional to H2S and CO2 concentrations and odor intensity, and inversely proportional to hedonic tone and SO2 concentration (P < 0.05). Releases of NH3, H2S, and CO2 were directly proportional (P < 0.05) to volatile solids loading rate (VSLR).
用于处理猪粪的厌氧 lagoons 的气味和气体排放会影响周边社区的空气质量,但排放速率尚未得到充分记录。使用一个浮力对流通量室(BCFC)来确定 lagoon 负荷率对在 1.0 m s(-1) 的模拟风速下从两个主要 lagoons 测量的气味和气体排放的影响。测量了 50-L 空气样本中氨(NH3)、硫化氢(H2S)、二氧化碳(CO2)、二氧化硫(SO2)和一氧化氮(NO)的浓度。一组经过认证参考气味剂验证其敏感性的人类受试者评估了气味浓度、强度和愉悦度。BCFC 入口和出口样本以及下风堤样本的几何平均气味浓度分别为 168 +/- 44(平均值 +/- 95% 置信区间)、262 +/- 60 和 114 +/- 38 OU(E) m(-3)(OU(E),欧洲气味单位,相当于 123 μg 正丁醇)。总体几何平均气味排放为 2.3 +/- 1.5 OU(E) s(-1) m(-2)(1.5 +/- 0.9 OU s(-1) m(-2))。活质量特定几何平均气味排放为 13.5 OU(E) s(-1) AU(-1)(动物单位 = 500 kg 活体质量)。总体平均 NH3、H2S、CO2 和 SO2 排放分别为 101 +/- 24、5.7 +/- 2.0、852 +/- 307 和 0.5 +/- 0.4 μg s(-1) m(-2)。未检测到一氧化氮。气味浓度与 H2S 和 CO2 浓度以及气味强度成正比,与愉悦度和 SO2 浓度成反比(P < 0.05)。NH3、H2S 和 CO2 的排放与挥发性固体负荷率(VSLR)成正比(P < 0.05)。