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在主要种植条件下及模拟模型生态系统中,土壤和小麦植株中砜嘧磺隆的消解情况

Dissipation of sulfosulfuron in soil and wheat plant under predominant cropping conditions and in a simulated model ecosystem.

作者信息

Ramesh Atmakuru, Maheswari Sinthalapadi Thulasiramaraja

机构信息

Department of Pesticide Chemistry, International Institute of Bio-Technology and Toxicology, Padappai, Chennai 601 301, Tamil Nadu, India.

出版信息

J Agric Food Chem. 2003 May 21;51(11):3396-400. doi: 10.1021/jf026137l.

Abstract

Environmental fate and dissipation of the sulfonylurea herbicide sulfosulfuron was investigated in soil (inceptisol) and wheat plant under predominant cropping conditions. Studies were conducted in natural field conditions and in a simulated model ecosystem. Thirty days after the wheat seeds had been sown, sulfosulfuron [N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-2-(ethylsulfonyl)imidazo[1,2-a]pyridine-3-sulfonamide] 75% w/w WG formulation was applied once in the field. The dosages were 25 and 50 g of active ingredient (ai)/ha. Studies were conducted in significantly separated individual plots to avoid contamination. In a predetermined interval, soil samples were collected and analyzed for the residues of sulfosulfuron. At harvest, wheat grain, straw, and soil samples were analyzed for the residues. Similar experiments were conducted in a model ecosystem. Apart from this, after harvest, the succeeding crops coriander (Coriandrum sativum) and edible amaranth (Amaranthus mangostanus L.) were raised in the model ecosystem and studied for the residues. No residues were detected in wheat grain, straw, and soil samples collected at harvest from both experiments or in the succeeding crops coriander and edible amaranth in the model ecosystem when tested at the minimum detection level of 0.001 microg/g. The dissipation of sulfosulfuron was found to have first-order kinetics in soil and plant in both studies. The dissipation data of sulfosulfuron in the model ecosystem were compared with those from the natural field conditions.

摘要

在主要种植条件下,研究了土壤(始成土)和小麦植株中磺酰脲类除草剂烟嘧磺隆的环境归宿和消解情况。研究在自然田间条件和模拟模型生态系统中进行。小麦种子播种30天后,在田间一次性施用75% w/w可湿性粉剂(WG)剂型的烟嘧磺隆[N-[[(4,6-二甲氧基-2-嘧啶基)氨基]羰基]-2-(乙基磺酰基)咪唑并[1,2-a]吡啶-3-磺酰胺]。施用量为25和50克活性成分(ai)/公顷。在显著分开的单个地块上进行研究以避免污染。在预定的时间间隔内,采集土壤样本并分析烟嘧磺隆的残留量。收获时,对小麦籽粒、秸秆和土壤样本进行残留分析。在模型生态系统中进行了类似的实验。除此之外,收获后,在模型生态系统中种植后续作物香菜(Coriandrum sativum)和苋菜(Amaranthus mangostanus L.)并研究其残留情况。在两个实验收获时采集的小麦籽粒、秸秆和土壤样本中,以及在模型生态系统中后续作物香菜和苋菜中,当检测限为0.001微克/克时,均未检测到残留。在两项研究中,均发现烟嘧磺隆在土壤和植物中的消解符合一级动力学。将模型生态系统中烟嘧磺隆的消解数据与自然田间条件下的数据进行了比较。

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