通过潜在亲核和亲电伙伴的协同活化实现催化烯酮环烯丙基化：有机催化与过渡金属催化的融合
Catalytic enone cycloallylation via concomitant activation of latent nucleophilic and electrophilic partners: merging organic and transition metal catalysis.
作者信息
Jellerichs Bradley G, Kong Jong-Rock, Krische Michael J
机构信息
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX 78712, USA.
出版信息
J Am Chem Soc. 2003 Jul 2;125(26):7758-9. doi: 10.1021/ja0301469.
PMID:12822967
Abstract
Upon exposure of mono-enone mono-allylic carbonates to tributylphosphine and 1 mol % Pd(Ph3P)4, efficient conversion to the corresponding cycloallylated products is achieved. This transformation combines the nucleophilic features of the Morita-Baylis-Hillman reaction with the electrophilic features of the Trost-Tsuji reaction.
摘要
将单烯酮单烯丙基碳酸酯暴露于三丁基膦和1 mol%的四(三苯基膦)钯时，可高效转化为相应的环烯丙基化产物。这种转化将森田-贝利斯-希尔曼反应的亲核特征与特罗斯特-辻反应的亲电特征结合在一起。
Zotero 插件