Disordered nanocrystalline superconducting PbMo6S8 with a very large upper critical field.

Large increases in the upper critical field B(C2)(0) are reported in bulk superconductors that demonstrate another novel property for nanocrystalline materials. Disordered nanocrystalline PbMo6S8 superconductors were fabricated by mechanical milling and hot isostatic pressing. Conventional PbMo6S8 has B(C2)(0) approximately 50 T. The nanocrystalline materials have higher resistivity (rho(N)) and B(C2)(0) approximately 100 T. The disorder produced in these nanocrystalline materials is significantly different from that produced by doping because it increases rho(N) and, hence, B(C2)(0) without significantly reducing the electronic density of states or superconducting transition temperature (T(C)). Furthermore, the disorder reduces the electron mean-free path to approximately 1 nm which is more than an order of magnitude smaller than the grain size and necessary to achieve the unprecedented increase in B(C2)(0).