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用于通过催化化学气相沉积法大规模合成准取向、高度石墨化的多壁碳纳米管束的双金属催化剂。

Bimetallic catalyst for synthesizing quasi-aligned, well-graphitized multiwalled carbon nanotube bundles on a large scale by the catalytic chemical vapor deposition method.

作者信息

Mukhopadhyay Kingsuk, Mathur Gyanesh Narayan

机构信息

Defence Materials and Stores Research and Development Establishment, DMSRDE Post Office, G.T. Road, Kanpur 208013, Uttar Pradesh, India.

出版信息

J Nanosci Nanotechnol. 2002 Apr;2(2):197-201. doi: 10.1166/jnn.2002.099.

Abstract

An effective method of growth by catalytic chemical vapor deposition (CCVD) to get a large-scale yield of carbon nanotubes is reported. In this method, acetylene is decomposed catalytically over well-dispersed metal particles (Co-Fe and Co-Ni) embedded in commercially available zeolite at a lower temperature (600-700 degrees C). The two binary-metal catalysts (Co-Fe and Co-Ni) used are compared by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Crucial reaction parameters, such as reaction time, temperature, and the effect of purity of gas to obtain optimum production of the nanotubes, both qualitatively and quantitatively, are also reported.

摘要

报道了一种通过催化化学气相沉积(CCVD)实现大规模生长碳纳米管的有效方法。在该方法中,乙炔在较低温度(600 - 700摄氏度)下于负载在市售沸石中的高度分散金属颗粒(钴 - 铁和钴 - 镍)上进行催化分解。通过扫描电子显微镜(SEM)和透射电子显微镜(TEM)对所使用的两种二元金属催化剂(钴 - 铁和钴 - 镍)进行了比较。还定性和定量地报道了关键反应参数,如反应时间、温度以及气体纯度对获得纳米管最佳产量的影响。

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