Bouchard M, Smith D C
Bâtiment Minéralogie, Muséum National d'Histoire Naturelle and CNRS, 61 Rue Buffon, 75005 Paris, France.
Spectrochim Acta A Mol Biomol Spectrosc. 2003 Aug;59(10):2247-66. doi: 10.1016/s1386-1425(03)00069-6.
Small catalogues of reference Raman spectra of interest for analysing geomaterials or biomaterials of relevance to art history or archaeology are gradually being published by different research groups. However, except for some older catalogues, they are all concerned primarily with pigments, whether inorganic or organic. Here we present for the first time a catalogue of Raman spectra of minerals that may be found in corroded metal artworks or artefacts. At the same time we include some inorganic pigments that may be found in or on stained glass. Most of the minerals analysed came from the Gallery of Mineralogy at the Muséum National d'Histoire Naturelle and most were verified by X-ray diffraction in order to augment the confidence in the mineral identity (which is not the case with many other catalogues). A number of problems encountered with mineral terminology are discussed. Comments are made on the spectra where appropriate.
不同研究小组逐渐出版了一些用于分析与艺术史或考古学相关的地质材料或生物材料的参考拉曼光谱小型目录。然而,除了一些较早的目录外,它们主要都关注颜料,无论是无机颜料还是有机颜料。在此,我们首次展示了一份可能在腐蚀的金属艺术品或手工艺品中发现的矿物拉曼光谱目录。同时,我们还纳入了一些可能在彩色玻璃内部或表面发现的无机颜料。分析的大多数矿物来自法国国家自然历史博物馆矿物学馆,并且大多数通过X射线衍射进行了验证,以增强对矿物鉴定的信心(许多其他目录并非如此)。讨论了矿物术语方面遇到的一些问题。并在适当的地方对光谱进行了评论。