新型精英阴离子配体：聚硫酰胺大环化合物。
Elite new anion ligands: polythioamide macrocycles.
作者信息
Hossain Md Alamgir, Kang Sung Ok, Llinares José M, Powell Douglas, Bowman-James Kristin
机构信息
Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA.
出版信息
Inorg Chem. 2003 Aug 25;42(17):5043-5. doi: 10.1021/ic034735r.
PMID:12924873
Abstract
Prototypes for a new class of polythioamide-based macrocycles have been synthesized and anion-binding capabilities assessed. Results indicate higher anion binding for H(2)PO(4)(-), HSO(4)(-), and F(-) for monocycles, but somewhat lessened binding capabilities for bicycles compared with amide corollaries.
摘要
一类新型基于聚硫酰胺的大环化合物的原型已被合成，并对其阴离子结合能力进行了评估。结果表明，单环对H(2)PO(4)(-)、HSO(4)(-)和F(-)具有更高的阴离子结合能力，但与酰胺类似物相比，双环的结合能力有所降低。
Zotero 插件