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Capture of Ni(II), Cu(I) and Z(II) by thiolate sulfurs of an N2S2Ni complex: a role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site.

作者信息

Golden Melissa L, Rampersad Marilyn V, Reibenspies Joseph H, Darensbourg Marcetta Y

机构信息

Texas A&M University, Department of Chemistry, College Station, Texas, USA.

出版信息

Chem Commun (Camb). 2003 Aug 7(15):1824-5. doi: 10.1039/b304884p.

DOI:10.1039/b304884p
PMID:12931985
Abstract

The metal binding affinity of an (N2S2)Ni bridging metallothiolate ligand (Zn2+ < Ni2+ < Cu+) gives precedent for the observed heterogeneity in ACS/CODH.

摘要

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引用本文的文献

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Structure, function, and biosynthesis of nickel-dependent enzymes.镍依赖酶的结构、功能和生物合成。
Protein Sci. 2020 May;29(5):1071-1089. doi: 10.1002/pro.3836. Epub 2020 Feb 18.
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双酰胺和混合胺/酰胺 NiN2S2 配合物作为含镍乙酰辅酶 A 合酶和超氧化物歧化酶的模型：实验和计算研究。
Inorg Chem. 2010 Jun 21;49(12):5393-406. doi: 10.1021/ic9023053.
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Synthetic analogs for evaluating the influence of N-H...S hydrogen bonds on the formation of thioester in acetyl coenzyme A synthase.用于评估N-H...S氢键对乙酰辅酶A合酶中硫酯形成影响的合成类似物。
Dalton Trans. 2009 Jun 14(22):4359-69. doi: 10.1039/b901192g. Epub 2009 Apr 27.
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Chemical issues addressing the construction of the distal Ni[cysteine-glycine-cysteine]2- site of acetyl CoA synthase: why not copper?关于乙酰辅酶A合酶远端Ni[半胱氨酸-甘氨酸-半胱氨酸]2位点构建的化学问题：为何不是铜？
Inorg Chem. 2009 Apr 6;48(7):2780-92. doi: 10.1021/ic801628r.
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Binuclear complexes containing a methylnickel moiety: relevance to organonickel intermediates in acetyl coenzyme A synthase catalysis.含有甲基镍部分的双核配合物：与乙酰辅酶A合酶催化中的有机镍中间体的相关性。
J Am Chem Soc. 2008 Oct 15;130(41):13510-1. doi: 10.1021/ja803795k. Epub 2008 Sep 19.
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Synthetic analogues of the active site of the A-cluster of acetyl coenzyme A synthase/CO dehydrogenase: syntheses, structures, and reactions with CO.乙酰辅酶A合成酶/一氧化碳脱氢酶A簇活性位点的合成类似物：合成、结构及与一氧化碳的反应
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Synthetic chemistry and chemical precedents for understanding the structure and function of acetyl coenzyme A synthase.用于理解乙酰辅酶A合成酶结构与功能的合成化学及化学先例。
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