Capture of Ni(II), Cu(I) and Z(II) by thiolate sulfurs of an N2S2Ni complex: a role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site.
作者信息
Golden Melissa L, Rampersad Marilyn V, Reibenspies Joseph H, Darensbourg Marcetta Y
机构信息
Texas A&M University, Department of Chemistry, College Station, Texas, USA.
出版信息
Chem Commun (Camb). 2003 Aug 7(15):1824-5. doi: 10.1039/b304884p.
DOI:10.1039/b304884p
PMID:12931985
Abstract
The metal binding affinity of an (N2S2)Ni bridging metallothiolate ligand (Zn2+ < Ni2+ < Cu+) gives precedent for the observed heterogeneity in ACS/CODH.
摘要
Zotero 插件