Zhang Fu-Shen, Itoh Hideaki
Research Center for Advanced Waste and Emission Management, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603, Japan.
J Hazard Mater. 2003 Aug 1;101(3):323-37. doi: 10.1016/s0304-3894(03)00208-5.
This study was carried out to prepare low-cost adsorbents from different types of waste ashes and post-consumer PET for use in industrial wastewater treatment. PET was melted and blended with ashes. The mixture was then carbonized to form different types of adsorbents. Heavy metal leaching from the adsorbents was greatly reduced compared to leaching from the bulk ashes. The BET surface area of the adsorbents ranged from 115 to 485m(2)/g. The acidic sites on the adsorbents varied from 0.84 to 1.56meq./g, higher than that of the PET carbon. The adsorption of methylene blue (MB) or heavy metals on the adsorbents was not in accordance with their surface areas because acidic sites reaction, affinity adsorption and cation exchange all contribute to the adsorption of the adsorbents. The isotherm for MB adsorption on the adsorbents can be well described by the Langmuir or Freundlich equation but heavy metal adsorption cannot. It is believed that the adsorbents produced in this manner can be used in wastewater treatments for discoloration and heavy metal removal.
本研究旨在利用不同类型的废灰和消费后聚对苯二甲酸乙二酯(PET)制备低成本吸附剂,用于工业废水处理。将PET熔化并与灰混合。然后将混合物碳化以形成不同类型的吸附剂。与散装灰的浸出相比,吸附剂的重金属浸出量大大降低。吸附剂的比表面积在115至485m²/g之间。吸附剂上的酸性位点在0.84至1.56meq./g之间变化,高于PET碳的酸性位点。亚甲基蓝(MB)或重金属在吸附剂上的吸附与其表面积不一致,因为酸性位点反应、亲和吸附和阳离子交换都有助于吸附剂的吸附。MB在吸附剂上的吸附等温线可以用Langmuir或Freundlich方程很好地描述,但重金属吸附则不能。据信,以这种方式生产的吸附剂可用于废水处理中的脱色和重金属去除。