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[取代二苯甲酮的抗心律失常活性脒腙。4. (Z)-和(E)-2-氨基-5-氯二苯甲酮脒腙及相应的(E)-N-苯基脒腙的光异构化]

[Antiarrhythmic active amidinohydrazones of substituted benzophenones. 4. The photoisomerization of (Z)- and (E)-2-amino-5-chlorobenzophenone amidinohydrazones and the corresponding (E)-N-phenylamidinohydrazone].

作者信息

Richter P H, Schleuder M, Geissler G, Tomaschewski G, Kasbohm K

机构信息

Fachbereich Pharmazie, Ernst-Moritz-Arndt-Universität Greifswald.

出版信息

Pharmazie. 1992 Dec;47(12):916-8.

PMID:1293615
Abstract

The title compounds undergo a photoisomerization by irradiation. If the E-isomers are irradiated by light of a wavelength of an absorption maximum typical for them, they can be converted quantitatively to the corresponding Z-isomers. In case that the synthesis of analogs of the title compounds give only one configurational isomer, sometimes the missing one can be obtained by photoisomerization.

摘要

标题化合物通过光照发生光异构化。如果用对它们而言典型的最大吸收波长的光照射反式异构体,它们可以定量地转化为相应的顺式异构体。倘若标题化合物类似物的合成仅得到一种构型异构体,有时缺失的异构体可通过光异构化获得。

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