Richter P H, Schleuder M, Geissler G, Tomaschewski G, Kasbohm K
Fachbereich Pharmazie, Ernst-Moritz-Arndt-Universität Greifswald.
Pharmazie. 1992 Dec;47(12):916-8.
The title compounds undergo a photoisomerization by irradiation. If the E-isomers are irradiated by light of a wavelength of an absorption maximum typical for them, they can be converted quantitatively to the corresponding Z-isomers. In case that the synthesis of analogs of the title compounds give only one configurational isomer, sometimes the missing one can be obtained by photoisomerization.
标题化合物通过光照发生光异构化。如果用对它们而言典型的最大吸收波长的光照射反式异构体,它们可以定量地转化为相应的顺式异构体。倘若标题化合物类似物的合成仅得到一种构型异构体,有时缺失的异构体可通过光异构化获得。