Chambers Richard D, Hoskin Philip R, Kenwright Alan R, Khalil Ali, Richmond Paul, Sandford Graham, Yufit Dmitrii S, Howard Judith A K
Department of Chemistry, University of Durham, South Road, Durham, UK DH1 3LE.
Org Biomol Chem. 2003 Jun 21;1(12):2137-47. doi: 10.1039/b303443g.
Perfluoro-4-isopropylpyridine was used as a building block for the two-step synthesis of a variety of macrocyclic systems bearing pyridine sub-units which were characterised by X-ray crystallography. Electrospray mass spectrometry revealed that complexation of either cations and, unusually, anions is possible depending on the structure of the macrocycle.
全氟-4-异丙基吡啶被用作构建单元，用于两步合成多种带有吡啶亚基的大环体系，这些体系通过X射线晶体学进行了表征。电喷雾质谱分析表明，根据大环的结构，阳离子以及不同寻常的阴离子都有可能发生络合。
