Radovan H A, Fortune N A, Murphy T P, Hannahs S T, Palm E C, Tozer S W, Hall D
NHMFL, Florida State University, Tallahassee, Florida 32310, USA.
Nature. 2003 Sep 4;425(6953):51-5. doi: 10.1038/nature01842.
Since the discovery of superconductivity, there has been a drive to understand the mechanisms by which it occurs. The BCS (Bardeen-Cooper-Schrieffer) model successfully treats the electrons in conventional superconductors as pairs coupled by phonons (vibrational modes of oscillation) moving through the material, but there is as yet no accepted model for high-transition-temperature, organic or 'heavy fermion' superconductivity. Experiments that reveal unusual properties of those superconductors could therefore point the way to a deeper understanding of the underlying physics. In particular, the response of a material to a magnetic field can be revealing, because this usually reduces or quenches superconductivity. Here we report measurements of the heat capacity and magnetization that show that, for particular orientations of an external magnetic field, superconductivity in the heavy-fermion material CeCoIn(5) is enhanced through the magnetic moments (spins) of individual electrons. This enhancement occurs by fundamentally altering how the superconducting state forms, resulting in regions of superconductivity alternating with walls of spin-polarized unpaired electrons; this configuration lowers the free energy and allows superconductivity to remain stable. The large magnetic susceptibility of this material leads to an unusually strong coupling of the field to the electron spins, which dominates over the coupling to the electron orbits.
自从发现超导现象以来,人们一直在努力理解其发生的机制。BCS(巴丁 - 库珀 - 施里弗)模型成功地将传统超导体中的电子视为通过声子(材料中的振动振荡模式)耦合的对,但对于高温超导、有机超导或“重费米子”超导,目前尚无被广泛接受的模型。因此,揭示这些超导体异常特性的实验可能为更深入理解其潜在物理机制指明方向。特别是,材料对磁场的响应可能具有启示意义,因为磁场通常会降低或抑制超导性。在此,我们报告了热容量和磁化强度的测量结果,结果表明,对于外部磁场的特定取向,重费米子材料CeCoIn(5)中的超导性通过单个电子的磁矩(自旋)得到增强。这种增强是通过从根本上改变超导态的形成方式实现的,导致超导区域与自旋极化未配对电子的壁交替出现;这种构型降低了自由能并使超导性保持稳定。这种材料的大磁化率导致磁场与电子自旋之间存在异常强的耦合,这种耦合超过了与电子轨道的耦合。