Monthoux P, Pines D, Lonzarich G G
School of Physics, University of Edinburgh, Edinburgh EH9 3JZ, UK.
Nature. 2007 Dec 20;450(7173):1177-83. doi: 10.1038/nature06480.
The idea of superconductivity without the mediating role of lattice vibrations (phonons) has a long history. It was realized soon after the publication of the Bardeen-Cooper-Schrieffer (BCS) theory of superconductivity 50 years ago that a full treatment of both the charge and spin degrees of freedom of the electron predicts the existence of attractive components of the effective interaction between electrons even in the absence of lattice vibrations--a particular example is the effective interaction that depends on the relative spins of the electrons. Such attraction without phonons can lead to electronic pairing and to unconventional forms of superconductivity that can be much more sensitive than traditional (BCS) superconductivity to the precise details of the crystal structure and to the electronic and magnetic properties of a material.
无晶格振动(声子)介导作用的超导概念有着悠久的历史。50年前,巴丁-库珀-施里弗(BCS)超导理论发表后不久人们就认识到,对电子的电荷和自旋自由度进行全面处理预测,即使在没有晶格振动的情况下,电子之间有效相互作用中也存在吸引成分——一个特殊例子是取决于电子相对自旋的有效相互作用。这种无声子的吸引可导致电子配对,并产生非常规形式的超导性,与传统(BCS)超导性相比,这种超导性可能对晶体结构的精确细节以及材料的电子和磁性质更为敏感。