Ligand-free Heck reaction: Pd(OAc)2 as an active catalyst revisited.
作者信息
Yao Qingwei, Kinney Elizabeth P, Yang Zhi
机构信息
Department of Chemistry and Biochemistry, The Michael Faraday Laboratories, Northern Illinois University, DeKalb, Illinois 60115-2862, USA.
出版信息
J Org Chem. 2003 Sep 19;68(19):7528-31. doi: 10.1021/jo034646w.
PMID:12968913
Abstract
Palladium acetate was shown to be an extremely active catalyst for the Heck reaction of aryl bromides. Both the base and the solvent were found to have a fundamental influence on the efficiency of the reaction, with K(3)PO(4) and N,N-dimethylacetamide being the optimal base and solvent, respectively.
摘要
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