James Stuart L
School of Chemistry, David Keir Building, Queen's University Belfast, Stranmillis Road, Belfast, Northern Ireland, UK BT9 5AG.
Chem Soc Rev. 2003 Sep;32(5):276-88. doi: 10.1039/b200393g.
Metal-organic frameworks are a recently-identified class of porous polymeric material, consisting of metal ions linked together by organic bridging ligands, and are a new development on the interface between molecular coordination chemistry and materials science. A range of novel structures has been prepared which feature amongst the largest pores known for crystalline compounds, very high sorption capacities and complex sorption behaviour not seen in aluminosilicate zeolites. The development of synthetic approaches to these materials and investigations of their properties are reviewed.
金属有机框架是一类最近才被发现的多孔聚合物材料，由通过有机桥连配体连接在一起的金属离子组成，是分子配位化学和材料科学界面上的一项新进展。已经制备出一系列新颖的结构，其特征在于具有已知晶体化合物中最大的孔、非常高的吸附容量以及在铝硅酸盐沸石中未见的复杂吸附行为。本文综述了这些材料的合成方法的发展及其性能研究。
