Operti Lorenza, Rabezzana Roberto
Dipartimento di Chimica Generale e Organica Applicata, Università degli Studi di Torino, Corso M d'Azeglio 48, 10125 Torino, Italy.
Mass Spectrom Rev. 2003 Nov-Dec;22(6):407-28. doi: 10.1002/mas.10065.
This review represents a general overview on the determination of bond energies in gas-phase organometallic systems. The paper focuses on articles published in the last 7 years, whose main scope was to experimentally measure metal ion-ligand binding energies. Therefore, studies of reactivity and characterization of ion complexes are not included, even if some of them display bond energies among the data measured. Bond energies are presented according to the metal ion complexed, in increasing order of atomic number. Periodic trends of binding energies and correlations among the various ligand are discussed. A brief summary of the most used techniques specifically devoted to gather bond energies is also provided.
本综述对气相有机金属体系中键能的测定进行了总体概述。本文重点关注过去7年发表的文章，其主要范围是通过实验测量金属离子-配体结合能。因此，即使其中一些研究在测量数据中显示了键能，但离子配合物的反应性和表征研究不包括在内。键能按照配位的金属离子，以原子序数递增的顺序呈现。讨论了结合能的周期性趋势以及各种配体之间的相关性。还简要总结了专门用于获取键能的最常用技术。
