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使用拉曼光谱和拉曼化学成像对避孕套润滑剂成分进行表征。

Characterization of condom lubricant components using Raman spectroscopy and Raman chemical imaging.

作者信息

Wolfe Julianne, Exline David L

机构信息

ChemImage Corporation, Pittsburgh, PA 15208, USA.

出版信息

J Forensic Sci. 2003 Sep;48(5):1065-74.

Abstract

A condom can be described as a protective sheath used as a contraceptive or to protect against sexually transmitted diseases. However, individuals also use condoms during the commission of sexual assaults to prevent identification through deposited biological material. Raman spectroscopy offers a novel approach to identifying the presence of condom lubricant components. Furthermore, Raman chemical imaging expands on conventional Raman spectroscopy to characterize multiple condom lubricant components simultaneously in a manner that effectively demonstrates heterogeneous sample mixtures both spectrally and spatially. Known reference materials, liquid and solid lubricant components of common condom brands were successfully characterized using Raman dispersive spectroscopy and Raman chemical imaging without extensive sample preparation inherent to other analytical methods. The characterization of these materials demonstrates the potential of this technique to become a routine screening method for condom lubricants. This preliminary investigation provides a basis for future studies to determine the feasibility of Raman spectroscopy and Raman chemical imaging for condom lubricant trace detection in case type samples.

摘要

避孕套可被描述为一种用作避孕工具或预防性传播疾病的保护套。然而,有些人在实施性侵犯时也会使用避孕套,以防止通过遗留的生物材料被识别。拉曼光谱法提供了一种识别避孕套润滑剂成分存在的新方法。此外,拉曼化学成像扩展了传统拉曼光谱法,能够同时对多种避孕套润滑剂成分进行表征,以一种能在光谱和空间上有效展示异质样品混合物的方式。使用拉曼色散光谱法和拉曼化学成像,无需其他分析方法固有的大量样品制备,就成功地对常见避孕套品牌的已知参考材料、液体和固体润滑剂成分进行了表征。这些材料的表征证明了该技术成为避孕套润滑剂常规筛查方法的潜力。这项初步研究为未来研究确定拉曼光谱法和拉曼化学成像用于案件类型样品中避孕套润滑剂痕量检测的可行性提供了基础。

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