三氟甲磺酸铟催化杂环芳烃与炔烃的双加成反应。
Indium triflate-catalysed double addition of heterocyclic arenes to alkynes.
作者信息
Tsuchimoto Teruhisa, Hatanaka Kyuya, Shirakawa Eiji, Kawakami Yusuke
机构信息
Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa 923-1292, Japan.
出版信息
Chem Commun (Camb). 2003 Oct 7(19):2454-5. doi: 10.1039/b308319e.
DOI:10.1039/b308319e
PMID:14587728
Abstract
Indium triflate was found to be a prominent catalyst for addition of heterocyclic arenes to alkynes to afford 2:1 adducts, where two heterocyclic arenes regioselectively attacked the same carbon atom of alkynes.
摘要
发现三氟甲磺酸铟是一种将杂环芳烃加成到炔烃上以生成2:1加合物的重要催化剂，其中两个杂环芳烃区域选择性地进攻炔烃的同一个碳原子。
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