Ranjbari Faride, Hemmati Salar, Rashidi Mohammad Reza
Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz Iran.
Drug Applied Research Centre, Tabriz University of Medical Sciences, Tabriz Iran.
Turk J Chem. 2021 Feb 17;45(1):42-49. doi: 10.3906/kim-2004-72. eCollection 2021.
Dipyrromethanes are useful mediator structures which can be used as a part of other molecules such as bis-porphyrins and their derivations. Various methods have been developed for their synthesis. This study presents the synthesis of a new bis-dipyrromethane, 7,12-bis(4-(di(1H-pyrrol-2-yl)methyl)phenyl)benzo[k]fluoranthene, using the Lewis acid catalyzed reaction between a new dialdehyde and pyrrole at room temperature. The UV spectroscopic and fluorometric properties of the final product and precursors were determined. The newly synthesized product with desirable UV spectroscopic and fluorometric properties has the potential to be applied as a part of bis-porphyrins or it can be used for other purposes in future studies.
二吡咯甲烷是有用的介导结构，可作为其他分子（如双卟啉及其衍生物）的一部分。已经开发出各种合成方法。本研究介绍了一种新型双二吡咯甲烷，即7,12-双（4-（二（1H-吡咯-2-基）甲基）苯基）苯并[k]荧蒽的合成，该合成是通过在室温下新型二醛与吡咯之间的路易斯酸催化反应实现的。测定了最终产物和前体的紫外光谱和荧光性质。新合成的产物具有理想的紫外光谱和荧光性质，有潜力作为双卟啉的一部分应用，或者在未来研究中用于其他目的。
