Knudsen Kristian Rahbek, Bachmann Stephan, Jørgensen Karl Anker
Danish National Research Foundation: Centre for Catalysis, Department of Chemistry, Aarhus University, DK-8000 Aarhus C, Denmark.
Chem Commun (Camb). 2003 Oct 21(20):2602-3. doi: 10.1039/b308395k.
The half-transamination reaction of alpha-keto esters with pyridoxamine or 4-picolylamine was found to be catalysed by different metal catalysts in organic solvents giving moderate yields and enantioselectivities of up to 37% ee for methyl-3-indole pyruvate.
发现α-酮酯与吡哆胺或4-甲基苄胺的半转氨反应在有机溶剂中由不同的金属催化剂催化，产率适中，丙酮酸甲酯-3-吲哚的对映体选择性高达37%ee。
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