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J Med Chem. 2011 Oct 27;54(20):7334-49. doi: 10.1021/jm200909u. Epub 2011 Sep 26.
3
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J Am Chem Soc. 2011 Aug 24;133(33):12914-7. doi: 10.1021/ja203138q. Epub 2011 Aug 3.
4
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J Am Chem Soc. 2011 Aug 17;133(32):12458-61. doi: 10.1021/ja205674x. Epub 2011 Jul 22.
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6
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7
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8
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9
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