Lavalette Arnaud, Tuna Floriana, Clarkson Guy, Alcock Nathaniel W, Hannon Michael J
Centre for Supramolecular and Macromolecular Chemistry, Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, UK CV4 7AL.
Chem Commun (Camb). 2003 Nov 7(21):2666-7. doi: 10.1039/b308963k.
Metal-ligand interactions are used not only to design metallo-supramolecular architectures but also to assemble multiple hydrogen bond sites at the periphery of these architectures. The hydrogen bond sites aggregate the architectures into polymeric arrays with the selection of anion determining whether this is self H-bond aggregation or anion-mediated H-bond aggregation.
金属-配体相互作用不仅用于设计金属超分子结构,还用于在这些结构的外围组装多个氢键位点。氢键位点将这些结构聚集为聚合物阵列,而阴离子的选择决定了这是自氢键聚集还是阴离子介导的氢键聚集。