Martins Alice, Wink Michael, Tei Andreas, Rauter Amélia P
Departamento de Química e Bioquímica, Faculdade de Ciências da Universidade de Lisboa, Ed. C8, 5o, Campo Grande, 1749-016 Lisboa, Portugal.
Z Naturforsch C J Biosci. 2003 Nov-Dec;58(11-12):776-8. doi: 10.1515/znc-2003-11-1203.
The alkaloid composition of the aerial parts of two taxa of Teline maderensis was studied by capillary GLC and GLC-MS. N-Methylcytisine was the major alkaloid found in both plants. Contents of cytisine and lupanine were higher in T. maderensis var. paivae while anagyrine content was more pronounced in T. maderensis var. maderensis. The alkaloids dehydrocytisine, N-acetylcytisine and epibaptifoline appeared only in T. maderensis var. maderensis and N-formylcytisine was identified as a minor constituent in T. maderensis var. paivae, and detected only in trace amounts in the other variety of the plant.
采用毛细管气相色谱法和气相色谱 - 质谱联用法对两种马德拉岩黄芪地上部分的生物碱成分进行了研究。N - 甲基金雀花碱是这两种植物中发现的主要生物碱。在马德拉岩黄芪变种派瓦中，金雀花碱和羽扇豆碱的含量较高，而在马德拉岩黄芪变种马德拉中，臭豆碱的含量更为显著。脱氢金雀花碱、N - 乙酰金雀花碱和表 baptifoline 仅出现在马德拉岩黄芪变种马德拉中，N - 甲酰金雀花碱被鉴定为马德拉岩黄芪变种派瓦中的次要成分，在该植物的另一个变种中仅检测到痕量。
