Topoleski L D, Ducheyne P, Cuckler J M
University of Pennsylvania, Department of Bioengineering, School of Engineering and Applied Science, Philadelphia 19104.
J Biomed Mater Res. 1992 Dec;26(12):1599-617. doi: 10.1002/jbm.820261206.
Fracture of the poly(methyl methacrylate) bone cement mantle can lead to the loosening and ultimate failure of cemented total joint prostheses. The addition of fibers to the bone cement increases fracture resistance and may reduce, if not eliminate, in vivo fracturing. This study discusses the effect of incorporating titanium (Ti) fibers on fracture toughness. Essential characteristics of the composite bone cement included a homogeneous and uniform fiber distribution, and a minimal increase in apparent viscosity of the polymerizing cement. Ti fiber contents of 1%, 2%, and 5% by volume increased the fracture toughness over non-reinforced bone cement by up to 56%. Bone cements of two different viscosities were used as matrix material, but when reinforced with the same fiber type and content, they showed no difference in fracture toughness. Four different fiber aspect ratios (68, 125, 227, 417) were tested. At 5% fiber content, there was no statistically significant dependence of fracture toughness on fiber aspect ratio. Scanning electron microscopy revealed important toughening mechanisms such as fiber/matrix debonding, local fracture path alteration, and ductile fiber deformation and fracture. Fiber fracture was evidence that the critical fiber length was exceeded. The surfaces of the Ti fibers were rough and irregular, indicating that a high degree of mechanical interlock between matrix and fiber was likely. The energy absorption contribution of plastic deformation and ductile fracture is absent in brittle fibers, like carbon, but is a distinction of the Ti fibers used in this study.
聚甲基丙烯酸甲酯骨水泥套的骨折会导致骨水泥固定的全关节假体松动并最终失效。在骨水泥中添加纤维可提高抗断裂性,并可能减少(如果不能消除的话)体内骨折。本研究讨论了掺入钛(Ti)纤维对断裂韧性的影响。复合骨水泥的基本特性包括纤维分布均匀且聚合物水泥的表观粘度增加最小。体积分数为1%、2%和5%的Ti纤维使骨折韧性比未增强的骨水泥提高了56%。使用了两种不同粘度的骨水泥作为基体材料,但用相同类型和含量的纤维增强时,它们的断裂韧性没有差异。测试了四种不同的纤维长径比(68、125、227、417)。在纤维含量为5%时,断裂韧性对纤维长径比没有统计学上的显著依赖性。扫描电子显微镜揭示了重要的增韧机制,如纤维/基体脱粘、局部断裂路径改变以及韧性纤维变形和断裂。纤维断裂表明超过了临界纤维长度。Ti纤维的表面粗糙且不规则,表明基体与纤维之间可能存在高度的机械互锁。塑性变形和韧性断裂的能量吸收贡献在像碳这样的脆性纤维中不存在,但这是本研究中使用的Ti纤维的一个特点。