Pourdeyhimi B, Wagner H D
Department of Textiles and Consumer Economics, University of Maryland, College Park 20742.
J Biomed Mater Res. 1989 Jan;23(1):63-80. doi: 10.1002/jbm.820230106.
A study of the fracture behavior of poly-(methyl methacrylate) (PMMA) bone cement reinforced with short ultra-high-molecular-weight polyethylene (Spectra 900) fibers is presented. Linear elastic and nonlinear elastic fracture mechanics results indicate that a significant reinforcing effect is obtained at fiber contents as low as 1% by weight, but beyond that concentration a plateau value is reached and the fracture toughness becomes insensitive to fiber content. The flexural strength and modulus are apparently not improved by the incorporation of polyethylene fibers in the acrylic cement, probably because of the presence of voids, the poor mixing practice and the weakness of the fiber/matrix interfacial bond. The present polyethylene/PMMA composite presents several advantages as compared to other composite cements, but overall the mechanical performance of this system resembles that of Kevlar 29/PMMA cement, with a few differences. Scanning electron microscopy reveals characteristic micromechanisms of energy absorption in Spectra 900/PMMA bone cement. A scheme for the strength of random fiber-reinforced composites, which is a simple extension of the Kelly and Tyson model for the strength of unidirectional composites, is presented and discussed. Young's modulus and the fracture toughness results are discussed in the framework of existing theories. More fundamental modeling treatments are needed in terms of fracture micromechanisms to understand and optimize the various mechanical properties with respect to structural parameters and cement preparation technique.
本文介绍了一项关于用短超高分子量聚乙烯(Spectra 900)纤维增强聚甲基丙烯酸甲酯(PMMA)骨水泥断裂行为的研究。线性弹性和非线性弹性断裂力学结果表明,在纤维含量低至1%(重量)时就能获得显著的增强效果,但超过该浓度后,就会达到一个平稳值,断裂韧性对纤维含量变得不敏感。在丙烯酸骨水泥中加入聚乙烯纤维后,弯曲强度和模量显然没有得到改善,这可能是由于存在孔隙、混合工艺不佳以及纤维/基体界面粘结较弱。与其他复合骨水泥相比,目前的聚乙烯/PMMA复合材料具有几个优点,但总体而言,该体系的力学性能与凯夫拉尔29/PMMA骨水泥相似,也有一些差异。扫描电子显微镜揭示了Spectra 900/PMMA骨水泥中能量吸收的特征微观机制。提出并讨论了一种随机纤维增强复合材料强度的方案,该方案是凯利和泰森单向复合材料强度模型的简单扩展。在现有理论框架内讨论了杨氏模量和断裂韧性结果。需要从断裂微观机制方面进行更基础的建模处理,以了解和优化与结构参数和骨水泥制备技术相关的各种力学性能。