Castanho M A, Brown W, Prieto M J
Centro de Quimica Fisica Molecular, Lisboa, Portugal.
Biophys J. 1992 Dec;63(6):1455-61. doi: 10.1016/S0006-3495(92)81733-2.
Micelles of cholesterol in aqueous solution have been investigated using polarized and depolarized dynamic light scattering. They are shown to be highly extended and characterized by a narrow size distribution. It is shown that a rod-like model is applicable with length, L = 580 nm. Determination of the rotational diffusion coefficient by analysis of the autocorrelation function gave a value of theta = 150 s-1, which is close to the calculated value for the rod with this dimension. Depolarized dynamic light scattering measurements as a function of angle gave a value of 110 s-1.
已使用偏振和去偏振动态光散射研究了胆固醇在水溶液中的胶束。结果表明,它们高度伸展且尺寸分布狭窄。研究表明,棒状模型适用,长度L = 580 nm。通过自相关函数分析确定的旋转扩散系数值为θ = 150 s-1,这与该尺寸棒的计算值相近。作为角度函数的去偏振动态光散射测量给出的值为110 s-1。