• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

A biomimetic pathway for hydrogen evolution from a model of the iron hydrogenase active site.

作者信息

Ott Sascha, Kritikos Mikael, Akermark Björn, Sun Licheng, Lomoth Reiner

机构信息

Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden.

出版信息

Angew Chem Int Ed Engl. 2004 Feb 13;43(8):1006-9. doi: 10.1002/anie.200353190.

DOI:10.1002/anie.200353190
PMID:14966893
Abstract
摘要

相似文献

1
A biomimetic pathway for hydrogen evolution from a model of the iron hydrogenase active site.一种从铁氢化酶活性位点模型析氢的仿生途径。
Angew Chem Int Ed Engl. 2004 Feb 13;43(8):1006-9. doi: 10.1002/anie.200353190.
2
Synthesis of the H-cluster framework of iron-only hydrogenase.仅含铁氢化酶H簇框架的合成。
Nature. 2005 Feb 10;433(7026):610-3. doi: 10.1038/nature03298.
3
Insights into the mechanism of electrocatalytic hydrogen evolution mediated by Fe2(S2C3H6)(CO)6: the simplest functional model of the Fe-hydrogenase active site.对Fe2(S2C3H6)(CO)6介导的电催化析氢机制的见解：铁氢化酶活性位点的最简单功能模型。
Inorg Chem. 2007 Jan 8;46(1):108-16. doi: 10.1021/ic061168+.
4
A biomimetic model for the active site of iron-only hydrogenases covalently bonded to a porphyrin photosensitizer.一种与卟啉光敏剂共价结合的仅含Fe氢化酶活性位点的仿生模型。
Angew Chem Int Ed Engl. 2006 Feb 6;45(7):1130-3. doi: 10.1002/anie.200503602.
5
Facile synthesis and functionality-dependent electrochemistry of Fe-only hydrogenase mimics.仅含Fe的氢化酶模拟物的简便合成及其功能依赖性电化学
Inorg Chem. 2008 Sep 15;47(18):8101-11. doi: 10.1021/ic800676y. Epub 2008 Aug 19.
6
Facilitated hydride binding in an Fe-Fe hydrogenase active-site biomimic revealed by X-ray absorption spectroscopy and DFT calculations.通过X射线吸收光谱和密度泛函理论计算揭示的铁-铁氢化酶活性位点仿生模型中促进氢化物结合的现象
Inorg Chem. 2007 Dec 24;46(26):11094-105. doi: 10.1021/ic701255p. Epub 2007 Nov 28.
7
Iron hydrogenase active site mimic holding a proton and a hydride.模拟铁氢化酶活性位点，容纳一个质子和一个氢化物。
Chem Commun (Camb). 2006 Feb 7(5):520-2. doi: 10.1039/b514280f. Epub 2005 Dec 20.
8
Synthesis and structure of a biomimetic model of the iron hydrogenase active site covalently linked to a ruthenium photosensitizer.
Angew Chem Int Ed Engl. 2003 Jul 21;42(28):3285-8. doi: 10.1002/anie.200351192.
9
A model system for [NiFe] hydrogenase maturation studies: Purification of an active site-containing hydrogenase large subunit without small subunit.用于[NiFe]氢化酶成熟研究的模型系统：不含小亚基的含活性位点氢化酶大亚基的纯化。
FEBS Lett. 2005 Aug 15;579(20):4292-6. doi: 10.1016/j.febslet.2005.06.064.
10
Monoiron hydrogenase catalysis: hydrogen activation with the formation of a dihydrogen, Fe-H(delta-)...H(delta+)-O, bond and methenyl-H4MPT+ triggered hydride transfer.单铁氢化酶催化作用：氢的活化伴随着二氢、Fe-H(δ-)...H(δ+)-O键的形成以及亚甲基-H4MPT+引发的氢化物转移。
J Am Chem Soc. 2009 Aug 12;131(31):10901-8. doi: 10.1021/ja902689n.

引用本文的文献

1
Hydrogen Oxidation by Bioinspired Models of [FeFe]-Hydrogenase.[铁铁]氢化酶的仿生模型催化氢氧化反应
ACS Org Inorg Au. 2024 Dec 3;5(2):105-116. doi: 10.1021/acsorginorgau.4c00073. eCollection 2025 Apr 2.
2
Facile electrocatalytic proton reduction by a [Fe-Fe]-hydrogenase bio-inspired synthetic model bearing a terminal CN ligand.通过带有末端氰基配体的[Fe-Fe]氢化酶仿生合成模型实现的简便电催化质子还原。
Chem Sci. 2024 Jan 1;15(6):2167-2180. doi: 10.1039/d3sc05397k. eCollection 2024 Feb 7.
3
Synthetic styrene-based bioinspired model of the [FeFe]-hydrogenase active site for electrocatalytic hydrogen evolution.
用于电催化析氢的基于苯乙烯的[FeFe]-氢化酶活性位点的合成仿生模型。
Sustain Energy Fuels. 2023 Aug 23;7(19):4967-4976. doi: 10.1039/d3se00409k. eCollection 2023 Sep 26.
4
Synthetic Organic Design for Solar Fuel Systems.太阳能燃料系统的合成有机设计
Angew Chem Int Ed Engl. 2020 Sep 28;59(40):17344-17354. doi: 10.1002/anie.202006013. Epub 2020 Jul 29.
5
Graphene Supported Rhodium Nanoparticles for Enhanced Electrocatalytic Hydrogen Evolution Reaction.用于增强电催化析氢反应的石墨烯负载铑纳米颗粒
Sci Rep. 2019 Nov 19;9(1):17027. doi: 10.1038/s41598-019-53501-x.
6
From protein engineering to artificial enzymes - biological and biomimetic approaches towards sustainable hydrogen production.从蛋白质工程到人工酶——实现可持续制氢的生物学和仿生学方法
Sustain Energy Fuels. 2018 Apr 1;2(4):724-750. doi: 10.1039/c7se00582b. Epub 2018 Feb 6.
7
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.利用第一行过渡金属配合物进行电驱动和太阳能驱动的燃料合成。
Chem Rev. 2019 Feb 27;119(4):2752-2875. doi: 10.1021/acs.chemrev.8b00392. Epub 2019 Feb 15.
8
FeS Cubane Type Cluster Immobilized on a Graphene Support: A High Performance H Evolution Catalysis in Acidic Water.固定在石墨烯载体上的立方烷型硫化铁簇：酸性水中的高性能析氢催化
Sci Rep. 2017 Dec 5;7(1):16948. doi: 10.1038/s41598-017-17121-7.
9
Computational investigation of [FeFe]-hydrogenase models: characterization of singly and doubly protonated intermediates and mechanistic insights.[铁铁]氢化酶模型的计算研究：单质子化和双质子化中间体的表征及机理洞察
Inorg Chem. 2014 Oct 6;53(19):10301-11. doi: 10.1021/ic5013523. Epub 2014 Sep 10.
10
[FeFe] hydrogenase: protonation of {2Fe3S} systems and formation of super-reduced hydride states.[铁铁]氢化酶：{2Fe3S}体系的质子化及超还原氢化物态的形成。
Angew Chem Int Ed Engl. 2014 Sep 15;53(38):10143-6. doi: 10.1002/anie.201406210. Epub 2014 Jul 30.