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A modular assembly of chiral oxazolinylcarbene-rhodium complexes: efficient phosphane-free catalysts for the asymmetric hydrosilylation of dialkyl ketones.

作者信息

Gade Lutz H, César Vincent, Bellemin-Laponnaz Stéphane

机构信息

Laboratoire de Chimie Organométallique et de Catalyse (UMR 7513), Institut Le Bel, Université Louis Pasteur, 4, rue Blaise Pascal, 67070 Strasbourg, France.

出版信息

Angew Chem Int Ed Engl. 2004 Feb 13;43(8):1014-7. doi: 10.1002/anie.200353133.

DOI:10.1002/anie.200353133
PMID:14966895
Abstract
摘要

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1
A modular assembly of chiral oxazolinylcarbene-rhodium complexes: efficient phosphane-free catalysts for the asymmetric hydrosilylation of dialkyl ketones.手性恶唑啉基卡宾-铑配合物的模块化组装：用于二烷基酮不对称硅氢化反应的高效无膦催化剂。
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Tuning of the structures of chiral phosphane-phosphites: application to the highly enantioselective synthesis of alpha-acyloxy phosphonates by catalytic hydrogenation.手性膦亚磷酸酯结构的调控：在催化氢化高对映选择性合成α-酰氧基膦酸酯中的应用。
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Enantiomerically pure rhodium complexes bearing 1,5-diphenyl-1,5-cyclooctadiene as a chiral diene ligand. Their use as catalysts for asymmetric 1,4-addition of phenylzinc chloride.以1,5-二苯基-1,5-环辛二烯作为手性二烯配体的对映体纯铑配合物。它们作为氯化苯基锌不对称1,4-加成反应催化剂的用途。
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