Jenkins Roger A, Ilgner Ralph H, Tomkins Bruce A, Peters Douglas W
Environmental Chemistry and Mass Spectrometry Group, Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA.
J Air Waste Manag Assoc. 2004 Feb;54(2):229-41. doi: 10.1080/10473289.2004.10470892.
Protocols have been developed and applied for the generation of aerosols that are likely to be comparable to those encountered in field settings for the calibration of easily transportable/portable real-time particle monitors. Aerosols generated were simulated environmental tobacco smoke, cedar wood smoke, cooking oil fumes, and propane stove particles. The time-integrated responses of three nephelometers and a monitor for particle-bound polynuclear aromatic hydrocarbons (PAH) were compared with gravimetric respirable suspended particulate matter (RSP) in a controlled-atmosphere chamber. In general, the monitor responses increased linearly with increasing mass concentration. However, the two monitors that reported mass per volume concentrations tended to overreport the actual RSP concentrations by factors up to 4.4. The real-time PAH monitor did not respond to cooking oil fumes, indicative of little PAH being present in the aerosol. One of the monitors that has been used in a variety of studies reported in the literature (DustTrak) was collocated with gravimetric RSP samplers in several hospitality venues in the Louisville, KY, area. Field studies indicated that the units overreported actual RSP concentrations by factors of 2.6-3.1, depending on whether the sampling was conducted in the nonsmoking or smoking sections of the facilities.
已经制定并应用了相关协议来生成气溶胶,这些气溶胶可能与在野外环境中遇到的气溶胶具有可比性,用于校准易于运输/便携的实时颗粒物监测仪。所生成的气溶胶包括模拟环境烟草烟雾、雪松烟雾、烹饪油烟和丙烷炉颗粒物。在可控气氛室内,将三台浊度仪和一台用于测定颗粒结合多环芳烃(PAH)的监测仪的时间积分响应与重量法可吸入悬浮颗粒物(RSP)进行了比较。总体而言,监测仪的响应随质量浓度的增加呈线性增加。然而,两台报告每体积质量浓度的监测仪往往会高估实际RSP浓度,高估倍数高达4.4。实时PAH监测仪对烹饪油烟没有响应,这表明气溶胶中存在的PAH很少。文献中报道的在各种研究中使用过的一台监测仪(DustTrak)与重量法RSP采样器在肯塔基州路易斯维尔地区的几个酒店场所进行了并置。实地研究表明,这些设备高估了实际RSP浓度,高估倍数在2.6至3.1之间,这取决于采样是在设施的无烟区还是吸烟区进行。