通过脯氨酸促进的碘化亚铜催化偶联反应合成芳基叠氮化物和乙烯基叠氮化物。
Synthesis of aryl azides and vinyl azides via proline-promoted CuI-catalyzed coupling reactions.
作者信息
Zhu Wei, Ma Dawei
机构信息
Department of Chemistry, Fudan University, Shanghai 200433, China.
出版信息
Chem Commun (Camb). 2004 Apr 7(7):888-9. doi: 10.1039/b400878b. Epub 2004 Mar 5.
DOI:10.1039/b400878b
PMID:15045114
Abstract
The coupling reaction of aryl halides or vinyl iodide with sodium azide under catalysis of CuI/L-proline works at relatively low temperature to provide aryl azides or vinyl azides in good to excellent yields.
摘要
在碘化亚铜/L-脯氨酸催化下，芳基卤化物或乙烯基碘化物与叠氮化钠的偶联反应在相对较低温度下进行，能以良好至优异的产率得到芳基叠氮化物或乙烯基叠氮化物。
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