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具有12元环孔口的新型开孔富勒烯:从孔口边缘去除有机加成物。

Novel open-cage fullerenes having a 12-membered-ring orifice: removal of the organic addends from the rim of the orifice.

作者信息

Vougioukalakis Georgios C, Prassides Kosmas, Orfanopoulos Michael

机构信息

Department of Chemistry, University of Crete, 71409 Iraklion, Greece.

出版信息

Org Lett. 2004 Apr 15;6(8):1245-7. doi: 10.1021/ol049843b.

DOI:10.1021/ol049843b
PMID:15070308
Abstract

Two novel open-cage fullerene derivatives bearing a 12-membered-ring orifice on the fullerene cage have been isolated. Removal of the N-MEM protective group leads to the first open-cage [60]fullerene derivative without organic addends on the rim of the orifice. [structure: see text]

摘要

已分离出两种在富勒烯笼上带有12元环孔的新型开孔富勒烯衍生物。N-MEM保护基团的去除产生了第一种在孔边缘没有有机添加剂的开孔[60]富勒烯衍生物。[结构:见正文]

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