Vougioukalakis Georgios C, Prassides Kosmas, Orfanopoulos Michael
Department of Chemistry, University of Crete, 71409 Iraklion, Greece.
Org Lett. 2004 Apr 15;6(8):1245-7. doi: 10.1021/ol049843b.
Two novel open-cage fullerene derivatives bearing a 12-membered-ring orifice on the fullerene cage have been isolated. Removal of the N-MEM protective group leads to the first open-cage [60]fullerene derivative without organic addends on the rim of the orifice. [structure: see text]
已分离出两种在富勒烯笼上带有12元环孔的新型开孔富勒烯衍生物。N-MEM保护基团的去除产生了第一种在孔边缘没有有机添加剂的开孔[60]富勒烯衍生物。[结构:见正文]