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具有11元、12元和13元环孔的开孔富勒烯衍生物：孔边缘有机加成物的化学转化

Open-cage fullerene derivatives having 11-, 12-, and 13-membered-ring orifices: chemical transformations of the organic addends on the rim of the orifice.

作者信息

Roubelakis Manolis M, Vougioukalakis Georgios C, Orfanopoulos Michael

机构信息

Department of Chemistry, University of Crete, Iraklion, Voutes 71003, Crete, Greece.

出版信息

J Org Chem. 2007 Aug 17;72(17):6526-33. doi: 10.1021/jo070796l. Epub 2007 Jul 27.

DOI:10.1021/jo070796l
PMID:17655360
Abstract

A novel open-cage [60]fullerene derivative, having two sulfur atoms on the rim of its 13-membered-ring orifice, has been isolated and characterized. Extensive studies on the N-MEM group reactivity of this as well as other previously reported open-cage [60]fullerene derivatives led to several new open-cage [60]fullerene adducts.

摘要

一种新型的开笼式[60]富勒烯衍生物已被分离和表征，其在13元环孔口边缘有两个硫原子。对该衍生物以及其他先前报道的开笼式[60]富勒烯衍生物的N-甲氧基甲基（N-MEM）基团反应性进行的广泛研究，得到了几种新的开笼式[60]富勒烯加合物。

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