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半柔性聚合物在向列型溶剂中的伸长与涨落

Elongation and fluctuations of semiflexible polymers in a nematic solvent.

作者信息

Dogic Z, Zhang J, Lau A W C, Aranda-Espinoza H, Dalhaimer P, Discher D E, Janmey P A, Kamien Randall D, Lubensky T C, Yodh A G

机构信息

Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.

出版信息

Phys Rev Lett. 2004 Mar 26;92(12):125503. doi: 10.1103/PhysRevLett.92.125503. Epub 2004 Mar 24.

Abstract

We directly visualize single polymers with persistence lengths l(p), ranging from 0.05 to 16 microm, dissolved in the nematic phase of rodlike fd virus. Polymers with a sufficiently large persistence length undergo a coil-rod transition at the isotropic-nematic transition of the background solvent. We quantitatively analyze the transverse fluctuations of the semiflexible polymers and show that at long wavelengths they are driven by the fluctuating nematic background. We extract the Odijk deflection length and the elastic constant of the background nematic phase from the data.

摘要

我们直接观察到了持久长度l(p)在0.05至16微米范围内、溶解于棒状fd病毒向列相中的单个聚合物。具有足够大持久长度的聚合物在背景溶剂的各向同性-向列相转变时会发生从卷曲到棒状的转变。我们定量分析了半柔性聚合物的横向涨落,并表明在长波长下,它们是由波动的向列相背景驱动的。我们从数据中提取了奥迪克偏转长度和背景向列相的弹性常数。

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