Marsili L, Focardi S
Dipartimento di Biologia Ambientale, Universita' di Siena, Via delle Cerchia 3, 53100 Siena, Italy.
Environ Pollut. 1996;91(1):1-9. doi: 10.1016/0269-7491(95)00037-r.
Polychlorinated biphenyls (PCBs) and DDT compounds were determined in subcutaneous blubber of fin whales (Balaenoptera physalus) and striped dolphins (Stenella coeruleoalba) from the Mediterranean Sea. From 1990 to 1993, 68 fin whale and 89 dolphin blubber biopsies were analysed. The whales were sampled while passing through the Ligurian Sea, whereas the dolphins were collected in different areas of the Mediterranean: the Ligurian, Tyrrhenian and Ionian Seas. Total PCBs and DDTs were 5.5-7.1 ppm and 4.2-9.5 ppm, respectively, in the whales and 15.5-86.0 ppm and 15.6-63.5 ppm, respectively, in the dolphins. Thirty PCB congeners were identified for each sample, IUPAC numbers 153, 138, 187, 180 and 170 being the most abundant, totalling an average of 55% of total PCBs in the whale and 60% in the dolphin. The large differences in accumulation are related to position in the food chain. In striped dolphins significant differences were found in relation to sampling site, and in fin whales in relation to sex.
对地中海长须鲸(Balaenoptera physalus)和条纹海豚(Stenella coeruleoalba)皮下脂肪中的多氯联苯(PCBs)和滴滴涕(DDT)化合物进行了测定。1990年至1993年期间,分析了68份长须鲸和89份海豚脂肪活检样本。长须鲸样本是在其穿越利古里亚海时采集的,而海豚样本则是在地中海的不同区域收集的:利古里亚海、第勒尼安海和爱奥尼亚海。长须鲸体内的多氯联苯总量和滴滴涕总量分别为5.5 - 7.1 ppm和4.2 - 9.5 ppm,海豚体内的相应含量分别为15.5 - 86.0 ppm和15.6 - 63.5 ppm。每个样本都鉴定出了30种多氯联苯同系物,其中国际纯粹与应用化学联合会(IUPAC)编号为153、138、187、180和170的同系物含量最高,在长须鲸体内它们总共平均占多氯联苯总量的55%,在海豚体内占60%。积累量的巨大差异与在食物链中的位置有关。在条纹海豚中,发现不同采样地点的积累量存在显著差异,在长须鲸中,积累量与性别有关。